Pressure dependence of the rate constants of diels-alder reactions and calculations of activation volumes
✍ Scribed by B. S. Él'yanov; S. K. Shakhova; G. A. Rubtsov
- Book ID
- 112488441
- Publisher
- Springer
- Year
- 1975
- Tongue
- English
- Weight
- 491 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1573-9171
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📜 SIMILAR VOLUMES
The pressure effect on the forward and backward rate constants and equilibrium constants of the Diels-Alder reaction of 9-chloroanthracene with tetracyanoethylene has been investigated in 1,2-dichloroethane up to 1000 kgcm -2 at 298.15 K. The reaction volume obtained from the pressure effect on equi
The activation and reaction volumes (∆V /∆V) were showing negative volumes of activation (∆V Ͻ 0) whereas the others are slightly retarded (∆V Ͼ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum