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Optically active 4-substituted cis-1,2-diphenylethylene oxides and related 1,2-diphenylethane diols

✍ Scribed by P.M. Dansette; H. Ziffer; D.M. Jerina


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
449 KB
Volume
32
Category
Article
ISSN
0040-4020

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Chemical synthesis of optically active c
✍ Takeshi Hanazawa; Sentaro Okamoto; Fumie Sato πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 64 KB

A variety of optically active 3-substituted cis-cyclohexane-3,5-dien-1,2-diol acetonides were readily prepared from chiral 5-(tert-butyldimethylsilyloxy)-2-cyclohexenone through a seven-step reaction in good overall yield. The synthesis also allowed preparation of the acetonide having an 2 H-atom at