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Optical Stability of Organometallic Compounds With a Tin-Germanium Bond

✍ Scribed by Marcel Gielen; Serge Simon


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
294 KB
Volume
86
Category
Article
ISSN
0037-9646

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## Abstract **A happy ending**: The germanium(II) hydride [LGeH], where L=[HC{(CMe)(2,6‐__i__Pr~2~C~6~H~3~N)}~2~], reacts with a diazoalkane to form the hydrazone derivative (see picture). The reaction proceeds through the unprecedented end‐on nitrogen insertion of the diazo compound.magnified imag