Synthesis, Spectroscopic Properties and Configurational Stability of Organometallic Compounds with a Tin-Iron Bond

✍ Scribed by Marcel Gielen; Cornells Hoogzand; Ivan van Den Eynde

• Publisher: Wiley (John Wiley & Sons)
• Year: 2010
• Weight: 214 KB
• Volume: 84
• Category: Article
• ISSN: 0037-9646
• DOI: 10.1002/bscb.19750841004

✦ Synopsis

Organotin compounds w i t h a t i n -i r o n bond are c o n f i g u r a t i o n a l l y stable w i t h i n t h e NMR time scale, even i n t h e presence o f nucleophiles. The spectroscopic properties o f (CH3) tC6H5C(CH3),CH,I(C6H5)Sn-Fe(CO)~(n-C5H5)t I, ( CH3)2 (C6H5)Sn-Fe( CO) ( n-C5H5) [ ( C6H5)3Pl, I I, and o f a s e r i e s o f compounds (C6H5),, (CH3)3-nSn-Fe(C0)2(n-C5H5), 111 (n=0,1,2,3) are described and discussed. This paper is part 51 o f the series Organometallic Compounds. For part SO, see r e f . (1).