✦ LIBER ✦
End-On Nitrogen Insertion of a Diazo Compound into a Germanium(II) Hydrogen Bond and a Comparable Reaction with Diethyl Azodicarboxylate
✍ Scribed by Anukul Jana; Sakya S. Sen; Herbert W. Roesky; Carola Schulzke; Sudipta Dutta; Swapan K. Pati
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 364 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
A happy ending: The germanium(II) hydride [LGeH], where L=[HC{(CMe)(2,6‐__i__Pr~2~C~6~H~3~N)}~2~], reacts with a diazoalkane to form the hydrazone derivative (see picture). The reaction proceeds through the unprecedented end‐on nitrogen insertion of the diazo compound.magnified image