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Optical resolution of ferrocene derivatives by liquid chromatography using aqueous cyclomaltohexaose as the mobile phase and polyamide as the stationary phase

✍ Scribed by Akira Harada; Kohji Saeki; Shigetoshi Takahashi

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 378 KB
Volume: 192
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(89)85159-6

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✦ Synopsis

1-Ferrocenylethanol and its analogues were completely resolved into their enantiomers by liquid chromatography on a polyamide column using aqueous cyclomaltohexaose (cY-cyclodextrin, (rCD) as the mobile phase. The stability constants (K,) for the inclusion complexes of aCD with each enantiomer of l-ferrocenylethanol, determined by liquid chromatography with various concentrations of (YCD, were 104~~' for (S)-ferrocenylethanol and 79~~~ for the (R) isomer. The temperature dependence of the resolution has been studied.

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