An approach has been developed which exploits the non aqueous enzymatic alcoholysis reaction for resolution of racemic stcrically hindered secondary alcohols. The method was used effectively in the first enzymatic preparation of both enantiomers of the title compound via porcine pancreatic lipase ca
โฆ LIBER โฆ
Optical resolution of 2,2,2-trifluoro-1-(9-phenanthryl)ethanol via enzymatic alcoholysis of its activated ester
โ Scribed by Katsuya Kato; Masato Katayama; Shozo Fujii; Haruhiko Fukaya; Hiroshi Kimoto
- Book ID
- 113397795
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 738 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0922-338X
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Aqueous micellar solutions containing cetyltrimethylammonium bromide (CTAB) and solubilized 2,2,2-trifluoro-1-( 9 -anthryl)-ethanol (TFAE) known to exhibit photorheological effects were investigated via (i) oscillatory shear viscometry, (ii) electrically induced birefringence, and (iii) dynamic ligh