Optical Micro-Characterization of Complex GaN Structures

✍ Scribed by J. Christen; T. Riemann

• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: English
• Weight: 632 KB
• Volume: 228
• Category: Article
• ISSN: 0370-1972
• DOI: 10.1002/1521-3951(200111)228:2<419::aid-pssb419>3.0.co;2-e

✦ Synopsis

Various techniques of pattern-controlled epitaxy like epitaxial lateral overgrowth (ELO) and lateral seeding epitaxy have successfully been used to overcome the lattice mismatch problem, however, resulting in a complex system of self-organized growth domains. For a detailed understanding a correlation of the structural, electronic, and optical properties on a micro-scale is mandatory. Scanning cathodoluminescence (CL) microscopy provides a powerful tool compiling low temperatures, spatial resolution Dx < 45 nm and high spectral resolution. ELO GaN on stripe patterned SiO 2 and W masks were characterized by CL microscopy, directly visualizing the formation of different growth domains: 1. the coherently grown regions between the stripes; 2. the ELO areas coalescing on the center of the masks and showing a blue shifted and strongly broadened CL where m-Raman evidences the reduction of local strain and probes the free carrier concentration which is dramatically changed over the masks; 3. the coalescence regions with poor epitaxial perfection including voids and strong incorporation of impurities; 4. the transition regions between 1. and 2. at the very edges of the masks characterized by high defect density and strongly blue shifted CL. Plan view CL directly images the local areas of improved crystal perfection only involving part of the total ELO regions. The formation of specific micro-domains in 5 mm thick crack-free Al 0.19 Ga 0.81 N, exhibiting different Al concentrations, during the initial stage of MOVPE grown on patterned GaN substrates and the transition to finally homogeneous growth is directly visualized by cross-sectional CL.