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Optical detection ESR for the nπ* triplet state of benzil

✍ Scribed by H. Hayashi; K. Morigaki; S. Nagakura

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
157 KB
Volume
9
Category
Article
ISSN
0009-2614

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✦ Synopsis

We have observed the ESR spectrum of tbe nlrC tsiplet state of benzii in a benzopbeaone singIe crystal with the optical detection me;fiod.

T he principal values and axes of its fine structure tensor are obtained. The fine structure parameters are 01= 0.092 cm-l and Ii!?/ = 0.

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Optically detected zero field magnetic r
Optically detected zero field magnetic resonance in the lowest triplet nπ* state of p-benzoquinone
✍ A.I. Attia; B.H. Loo; A.H. Francis 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 492 KB

Optically detected magnetic resonance (ODMR) techniques are used to determine the orbital asQnment of the phosphorescent triplet state of p-benzoquinone in the condensed phase. The principal spin-orbit coupl% routes are discussed in terms of the observed spin-vibronic activity.