EPR studies of n-π* triplet states and the comparison of the n-π* triplet states of aromatic carbonyl compounds
✍ Scribed by Noboru Hirota
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 332 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
Scmi-cmpnlck~l calculations dre rcportcd for the lowest nn\* and BIT\* clcctromc triplet statcs of berwaldchydc. IIqulhbrmm gcomctrws, spin drpole-dlpolc and spin-orbIt contributions to the 2I.S paramcterr; ns well .IS oscillator strcngthP 1) + SO arc presented and discussed for both states.
We have observed the ESR spectrum of tbe nlrC tsiplet state of benzii in a benzopbeaone singIe crystal with the optical detection me;fiod. T he principal values and axes of its fine structure tensor are obtained. The fine structure parameters are 01= 0.092 cm-l and Ii!?/ = 0.