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Optical and ESR spectra of one-electron oxidized lead(II)tetraphenylporphyrin produced by γ-radiolysis and photolysis in 1,1,2,2-tetrachloroethane solutions at 77 K

✍ Scribed by Mikio Hoshino; Shiro Konishi; Kiyoharu Ito; Masashi Imamura

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 279 KB
Volume: 88
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83355-1

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✦ Synopsis

The nlion rJdinl of Icad(ll)Ictraphenylporphyrin W;IS produced by yndlolysisnnd by photolysis of the 1,1.2,2-tetrachloroethanc solutions at 77 K. The hfcc (0 0391 c~') dot to paired electron IS predommantly located m the porphyry ring. "'Pb observed in the CSR spectrum mduates lhat the un-1. introduction Synthetic metalloporphyrms

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