✦ LIBER ✦

Optical absorption and quartet ESR spectra of one-electron reduced nitric oxide adduct of manganese(II) tetraphenylporphyrins in rigid solution at 77 K

✍ Scribed by Mikio Hoshino; Shiro Konishi

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 395 KB
Volume: 115
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)85181-2

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✦ Synopsis

The S = 3/2 ESR spectrum is observed for the one-electron reduced species of the nitric oxide adduct of manganese0 tetraphenylporphyrin in 2-methyltetrahydrofuran solution produced by -y-irradiation at 77 IL The optical absorption and ESR spectra indicate that an excess electron Zs captured by the central manganese atom.

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