Absorption spectroscopic and ESR studies on one-electron reduction products of copper(II) and oxovanadium(IV) tetraphenylporphyrins produced by γ-radiolysis in 2-methyltetrahydrofuran solutions at 77 K

Optical and ESR spectra of one-electron

Optical and ESR spectra of one-electron oxidized lead(II)tetraphenylporphyrin produced by γ-radiolysis and photolysis in 1,1,2,2-tetrachloroethane solutions at 77 K

✍ Mikio Hoshino; Shiro Konishi; Kiyoharu Ito; Masashi Imamura 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 279 KB

The nlion rJdinl of Icad(ll)Ictraphenylporphyrin W;IS produced by yndlolysisnnd by photolysis of the 1,1.2,2-tetrachloroethanc solutions at 77 K. The hfcc (0 0391 c~') dot to paired electron IS predommantly located m the porphyry ring. "'Pb observed in the CSR spectrum mduates lhat the un-1. introdu