Optical and electrical characterization of hafnium oxide deposited by MOCVD
β Scribed by Y. Lu; O. Buiu; S. Hall; P. K. Hurley
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 228 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0026-2714
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β¦ Synopsis
The paper reports on electrical and optical investigations performed on HfO 2 high-k films deposited by Metalorganic chemical vapor deposition (MOCVD). Spectroellipsometry investigations show the presence of a transition layer between HfO 2 and the silicon substrate, which can be optically modelled as a mixture of Si and SiO 2 ; this information is further used in the assessment of the electrical measurements. Hysteresis effects have been observed in the Capacitance-Voltage (C-V) measurements for the as-deposited sample as well as the annealed samples. For the samples with large hysteresis, Poole-Frenkel (PF) conduction is the most likely dominant conduction mechanism. The energy of dominant trap level was found to be $0.7 eV.
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## Abstract Thin films of antimony and antimony oxides have been deposited by metalβorganic (MO) CVD from a variety of metalβorganic precursors at temperatures in the range 150β650βΒ°C under both atmospheric and reduced pressure. Below 400βΒ°C, uniform films of pure senarmontite (Sb~2~O~3~) with a mi