On the synthesis of bis(pentafluorosulfur) peroxide
β Scribed by Edward F. Witucki
- Publisher
- Elsevier Science
- Year
- 1969
- Weight
- 167 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0020-1650
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π SIMILAR VOLUMES
The thermal decomposition of SFsOsSFs in the presence of CO has been investigated between -9.8"C and + 9.9"C. Besides traces of S2F10, equimolecular amounts of SFsOrSFs ;ind CO? are formed. The reaction is homogeneous. Its rate is proportional to the pressure of the trioxide and independent of the
## Abstract The literature results for the pyrolysis of bis trifluoromethyl peroxide are reexamined and compared with those for dimethyl peroxide. The thermochemistry yields the result that the Οβbond energy in carbonyl fluoride is 96 Β± 10 kcal/mol compared to 74 kcal/mol for that in formaldehyde.