The thermal emf of alkali metal-alkali halide mixtures is calculated on the basis of two models, the Pitzr model which suggests that the metal is completely dissociated to cation and electron, and the Rice model which assumes no dissociation. The Rice model gives surprisingly good agreement with the
On the structure factor of metal-molten salt solutions
β Scribed by J. Wiechen; F. Brouers
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 133 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
We show that in contrast to MSA the HNC approximation can account qualitatively for the long wavelength scattering of metal-molten salt solutions. The difference is attributed to the defects of the MSA in the description of the short-range as well as the long-range order in the liquid.
π SIMILAR VOLUMES
N,O, reacts with 02-ion in LiCl-KC1 eutectic at 450" to give NO,-. By analogy to the salts of the other oxides of Group V, NO,-can be considered as metanitrate and is expected to giveunder appropriate conditions-the corresponding pyro-salt. Experiments are described in which the 02-ion in LiCl-KC1 m