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The thermal emf of alkali metal—molten salt mixtures

✍ Scribed by K.E. Johnson; S.J. Sime

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
350 KB
Volume
22
Category
Article
ISSN
0013-4686

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✦ Synopsis

The thermal emf of alkali metal-alkali halide mixtures is calculated on the basis of two models, the Pitzr model which suggests that the metal is completely dissociated to cation and electron, and the Rice model which assumes no dissociation. The Rice model gives surprisingly good agreement with the only available datum, that for Cs in CsAu. It is suggested that these systems will show a significant improvement in the figure of merit over simple molten salt mixtures.

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