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On the stereochemistry of vicinal nucleophilic substitution of β-(phosphatoxy)alkyl radicals

✍ Scribed by David Crich; Stéphane Gastaldi

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
172 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

It is demonstrated by means of diastereomeric probes that the vieinal nuclcophilic displacement of a diethylphosphat¢ group from a I$-(phosphatoxy)alkyl radical may take place by backside or frontside attack depending on stcrie constraints

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