The influence of alkoxy groups on the nucleophilicity of alkyl radicals
✍ Scribed by Bernd Giese; Jacques Dupuis; Thomas Haßkerl; Jürgen Meixner
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 157 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
It is demonstrated by means of diastereomeric probes that the vieinal nuclcophilic displacement of a diethylphosphat¢ group from a I$-(phosphatoxy)alkyl radical may take place by backside or frontside attack depending on stcrie constraints
## Abstract **Summary:** The benzene solution polymerizations of __tert__‐butyl acrylate (__t__BA) and 2‐ethylhexyl acrylate (EHA) have been investigated with respect to the effects of mid‐chain radicals (MCRs) on the rate of polymerization, the total radical concentration, the apparent rate coeffi