On the stereochemistry of coronatine : revised absolute configuration of (+)-coronamic acid
โ Scribed by Akitami Ichihara; Kunio Shiraishi; Sadao Sakamura; Ako Furusaki; Nobuhiro Hashiba; Takeshi Matsumoto
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 195 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
In the previous paper, we reported the stereochemistry of coronatine 1) , in which amino acid part, (+) -coronamic acid, was described as the enantiomer ofA on the basis of application of sector rule. 3) In this communication, we would like to describe further investigation on the stereochemistry of coronamic acid, and we are forced to conclude that the absolute configuration should be revised as l_by the enzymatic method 3) and X-ray analysis, and total stereostructure of
๐ SIMILAR VOLUMES
The structure of hippospongic acid A was reinvestigated and new evidence supporting the revised structure previously proposed was obtained. The structure, including absolute configuration, was established by the enantioselective synthesis.
independent molecules). Enraf-Nonius CAD4 diffractometer, monochrom a r i x d Mok,, radiation, 4292 independent reflections with 2.0=s//s22.0', full matrix refinement with 2616 reflections [f>2cT(f)]; R=0.0676, R,,=0.0491 [~==.(o'+O.O009F:,)-']. Further details of the cryztal structure investigation