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On the stereochemistry of coronatine : revised absolute configuration of (+)-coronamic acid

โœ Scribed by Akitami Ichihara; Kunio Shiraishi; Sadao Sakamura; Ako Furusaki; Nobuhiro Hashiba; Takeshi Matsumoto


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
195 KB
Volume
20
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


In the previous paper, we reported the stereochemistry of coronatine 1) , in which amino acid part, (+) -coronamic acid, was described as the enantiomer ofA on the basis of application of sector rule. 3) In this communication, we would like to describe further investigation on the stereochemistry of coronamic acid, and we are forced to conclude that the absolute configuration should be revised as l_by the enzymatic method 3) and X-ray analysis, and total stereostructure of


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