On the Absolute Configuration of (+)-Tartaric Acid

✍ Scribed by Dr. Hartmuth Buding; Prof. Dr. Bertold Deppisch; Prof. Dr. Hans Musso; Prof. Dr. Günther Snatzke

• Publisher: John Wiley and Sons
• Year: 1985
• Tongue: English
• Weight: 133 KB
• Volume: 24
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198505131

✦ Synopsis

independent molecules). Enraf-Nonius CAD4 diffractometer, monochrom a r i x d Mok,, radiation, 4292 independent reflections with 2.0=s//s22.0', full matrix refinement with 2616 reflections [f>2cT(f)]; R=0.0676, R,,=0.0491 [~==.(o'+O.O009F:,)-']. Further details of the cryztal structure investigation are available on request from the Fachinforrnationszentrum Energie Physik Mathematik, D-75 14 Eggenstein-Leopoldshafen 2 on quoting the depository number CSD 51 288, the names of the authors and the full citation of the journal. ton effect that is ubserved.['I The ( R , R ) configuration of ( + ) -1 and the ( S , S , S , S ) configuration of ( + ) -4 are linked here by the structure determination of 5 . In this way (R,R)-( +)-1 is reconfirmed through the optical activity of (S,S,S,S)-4.