The CD exciton chirality method was applied to determine the absolute stereochemistry of the strevertenes, antifungal pentaene macrolides produced by Streptoverticillium sp. LL-30F848. The CD difference spectrum of strevertene A methyl ester 15-dimethylaminobenzoate showed a positive couplet between
The Absolute Stereochemistry of Cascarillic Acid.
β Scribed by Ieuan O. Roberts; Mark S. Baird; Ying Liu
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 9 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The absolute stereochemistry of the 2-hydroxyglutaric acid present in methanopterin and its β£-glutamyl derivative, sarcinapterin, has been determined to be (S). Thus, the absolute stereochemistry of the 2-hydroxyglutaric acid present in the side chain of these modified folates is the same as the L-g
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## Abstract For Abstract see ChemInform Abstract in Full Text.