The resonance stabilization energies, Es, of polyenyl radicals can be estimated by the equation E,(N) = -13.2+ [ 3.95 -15.8 (2) -2/n] kcal mol -I, where N is the number of C, C-x bonds in the polyenyl radicals. This correlation has been extended for predicting the weakest H-C, C-C and C-OH bond diss
On the stabilization energy of α-methoxyalkyl radicals
✍ Scribed by Hermann Birkhofer; Hans-Dieter Beckhaus; Christoph Rüchardt
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 218 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
A stabilization energy of 1.5-2.0 kcal.mol -1 is estimated for a-methoxyalkyl radicals from the strain enthalpies and the free enthalpies of thermal decomposition of three glycol ethers A.
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