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On the configurational equilibration of α-chlorocyclopropyl and α-fluorocyclobutyl radicals.

✍ Scribed by L.J. Altman; Robert C. Baldwin

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
165 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

We have been prompted to investigate the effects of a-substituents on the inversion barriers of radicals 1 by the large difference in configurational stability between the unsubstituted cyclopropyl radicalA and an a-fluorocyclopropyl radical.3 We report here our results on the inversion rates of an a-chlorocyclopropyl and an a-fluorocyclobutyl radical.

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