✦ LIBER ✦

The stabilization energies of polyenyl radicals

✍ Scribed by Yu-Ran Luo; John L. Holmes

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 277 KB
Volume: 228
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00943-0

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✦ Synopsis

The resonance stabilization energies, Es, of polyenyl radicals can be estimated by the equation E,(N) = -13.2+ [ 3.95 -15.8 (2) -2/n] kcal mol -I, where N is the number of C, C-x bonds in the polyenyl radicals. This correlation has been extended for predicting the weakest H-C, C-C and C-OH bond dissociation energies in vitamin A and similar compounds.

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