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On the reactivity of 9-chloro-9-phenyl-bicyclo(3.3.1)nonane

โœ Scribed by L. Baiocchi; M. Giannangeli; G. Palazzo


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
109 KB
Volume
12
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Ethanolysis of tertiary 9-chloro-bicyclo
โœ L. Baiocchi; M. Giannangeli; G. Palazzo ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 171 KB

The solvolysis rates of a series of tertiary&-aryl-substituted cycloalkyl chlorides were recently determined (1). This series did not include 9-substituted-bicyclo(3.3.1)nonanes, the only available data being on the acetolysis of secondary tosylates, from which many rearranged products are obtained

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A Practical Synthesis of Bicyclo[3.3.1]nonan-9-one. -A new protocol for the synthesis of title compound (VII) is presented. It uses inexpensive and readily available reagents, involves no purification of intermediates and can be carried through on a โ‰ˆ20 g product scale in 47% yield. -(TAESCHLER,