The solvolysis rates of a series of tertiary&-aryl-substituted cycloalkyl chlorides were recently determined (1). This series did not include 9-substituted-bicyclo(3.3.1)nonanes, the only available data being on the acetolysis of secondary tosylates, from which many rearranged products are obtained
On the reactivity of 9-chloro-9-phenyl-bicyclo(3.3.1)nonane
โ Scribed by L. Baiocchi; M. Giannangeli; G. Palazzo
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 109 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Lanthanide shift reagents have been used for the conformational analysis of bicyclo[3.3.1]nonan-g-one. Comparison of predicted shifts and experimental values obtained with Eu(fod)3 indicate that the boat-chair conformation constitutes 22% of the mixture of conformers. Bicyclo[3.3.l]nonane (1) and it
A Practical Synthesis of Bicyclo[3.3.1]nonan-9-one. -A new protocol for the synthesis of title compound (VII) is presented. It uses inexpensive and readily available reagents, involves no purification of intermediates and can be carried through on a โ20 g product scale in 47% yield. -(TAESCHLER,