A Practical Synthesis of Bicyclo[3.3.1]nonan-9-one. -A new protocol for the synthesis of title compound (VII) is presented. It uses inexpensive and readily available reagents, involves no purification of intermediates and can be carried through on a β20 g product scale in 47% yield. -(TAESCHLER,
Microwave spectrum and conformation of bicyclo[3,3,1]-nonan-9-one
β Scribed by Ying-Sing Li; San Li
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 322 KB
- Volume
- 213
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
Condensation of substituted cyclohexanones with cinnamaldehydes and morpholine in the presence of anhydrous cerium(II1) chloride was carried out. The stereochemistry of the condensed products, variously substituted 2morpholino-4-phenylbicyclo[3.3.l]nonan-9-ones, was deduced by using the 'H NMR COSY
## Abstract Carbonβ13 NMR spectra of solid polycrystalline bicyclo[3.3.1]nonanβ9βone and adamantanone have been measured at 315K. The relatively narrow ^13^C linewidths observed for these solids, together with measured spinβlattice relaxation times, indicate that both these solids are orientational