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On the reaction of trisubstituted olefins with phenylselenenyl chloride in methanol

✍ Scribed by P. Ceccherelli; M. Curini; M.C. Marcotullio; O. Rosati

Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 474 KB
Volume: 47
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86457-7

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✦ Synopsis

The interaction of trisubstituted olefins with excess phenylselenenyl chloride in methanol generates chloromethoxy and dimethoxyderivatives. The mechanism of this transformation has been investigated.

Phenylselenenyl chloride is known to react with olefins to produce, in an anti-stereospecific fashion, the /?-chloro-,l fl-hydroxy-,' or ,!&methoxy-selenides3 depending on the reaction conditions. The removal of the selenium containing moiety from these adducts can be achieved, inter

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