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Nature of the intermediates in the reaction of palladium chloride with olefins

✍ Scribed by R. Baker; D.E. Halliday; T.J. Mason

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
217 KB
Volume
11
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

On the question of carbonium ion interme
On the question of carbonium ion intermediates in the palladium (II) chloride-copper (II) chloride catalyzed addition reactions of bycyclic olefins
✍ Charles J.R. Adderley; J.W. Nebzydoski; Merle A. Battiste; R. Baker; D.E. Hallid πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 187 KB

In a recent communication the palladium (II) chloride catalyzed addition reactions of olefins 1 and 2, -in the presence of CuClz/AcONa-AcOH, were

Reaction of olefin-palladium chloride co
Reaction of olefin-palladium chloride complex with carbon monoxide.
✍ J. Tsuji; M. Morikawa; J. Kiji πŸ“‚ Article πŸ“… 1963 πŸ› Elsevier Science 🌐 French βš– 157 KB

Reaction of olefin-palladium chloride complex with water to form a carbonyl compound is well known and acetaldehyde is produced industrially from ethylene by the catalytic action of palladium chloride. By the elaborate work of Smidt on the mechanism of this reaction, 1 it was firmly established that

On the reaction of trisubstituted olefin
On the reaction of trisubstituted olefins with phenylselenenyl chloride in methanol
✍ P. Ceccherelli; M. Curini; M.C. Marcotullio; O. Rosati πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 474 KB

The interaction of trisubstituted olefins with excess phenylselenenyl chloride in methanol generates chloromethoxy and dimethoxyderivatives. The mechanism of this transformation has been investigated. Phenylselenenyl chloride is known to react with olefins to produce, in an anti-stereospecific fash