A detailed investigation into the influence of phosphines, additives, bases and solvents on the Heck coupling reaction of 4-trifluoromethyl-1-chlorobenzene (2) is presented. It is shown that a number of catalyst systems exist for efficient cross coupling of electron-deficient aryl chlorides with var
The Oxidation of Olefins with Palladium Chloride Catalysts
β Scribed by Dr. Juergen Smidt; Dr. W. Hafner; Dr. R. Jira; Dr. R. Sieber; Dr. J. Sedlmeier; Dr. A. Sabel
- Publisher
- John Wiley and Sons
- Year
- 1962
- Tongue
- English
- Weight
- 843 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0044-8249
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This paper describes a study of the kinetics of oxidation of hydrogen chloride over unsupported melts containing copper, potassium and lanthanum chlorides. It is shown that kinetic data may be interpreted by assuming that the equilibrium: CuCl, = CUCI + Cl, is maintained at all times between catalys