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On the reaction of P4S10 with hexamethyldisilazane

✍ Scribed by Jiri Pinkas; John G. Verkade

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 224 KB
Volume: 9
Category: Article
ISSN: 1042-7163
DOI: 10.1002/(sici)1098-1071(1998)9:2<115::aid-hc3>3.0.co;2-b

No coin nor oath required. For personal study only.

✦ Synopsis

P 4 S 10 reacts with (Me 3 Si) 2 NH, to give SP(NHSi-Me 3 ) x (SSiMe 3 ) 3‫מ‬x , where x ‫ס‬ 0-3. These species were shown by 31 P NMR spectroscopy to subsequently form cyclic and linear condensation products. The molecular structure of a linear trimer (Me 3 SiNH)P(S)[(l-NH)P(S)(NHSiMe 3 ) 2 ] 2 , 12, was authenticated by an Xray diffraction study.

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