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A study on the sublimation behaviour of solid P4S10

โœ Scribed by R. Gigli; V. Piacente; P. Scardala


Publisher
Springer
Year
1990
Tongue
English
Weight
169 KB
Volume
9
Category
Article
ISSN
0261-8028

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On the reaction of P4S10 with hexamethyl
โœ Jiri Pinkas; John G. Verkade ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 224 KB ๐Ÿ‘ 1 views

P 4 S 10 reacts with (Me 3 Si) 2 NH, to give SP(NHSi-Me 3 ) x (SSiMe 3 ) 3โ€ซืžโ€ฌx , where x โ€ซืกโ€ฌ 0-3. These species were shown by 31 P NMR spectroscopy to subsequently form cyclic and linear condensation products. The molecular structure of a linear trimer (Me 3 SiNH)P(S)[(l-NH)P(S)(NHSiMe 3 ) 2 ] 2 , 1