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On the reaction of glycidol with a secondary amine

โœ Scribed by Ewa Witek; Andrzej Kochanowski; Edgar Bortel


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
74 KB
Volume
21
Category
Article
ISSN
1022-1336

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๐Ÿ“œ SIMILAR VOLUMES


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Kinetic studies established that the monomethylation of a primary amine leads to significantly higher reaction rates with glycidyl ethers. The relative rates for approximately 25 amines were determined in an alcohol solvent under pseudo-firstorder conditions (excess epoxy). The rates were referenced

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The title reactions are subjected to a kinetic analysis in ethanol-water, at 44 wt% ionic strength 0.2 (KCl). With a large excess of amine over the substrate, pseudo-first-25.0ะŠC, order rate coefficients are obtained, which are linearly dependent on the amine concen-(k ) obs tration. The nucleophili