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Anionic synthesis of secondary amine functionalized polymers by reaction of polymeric organolithiums with N-benzylidenemethylamine

โœ Scribed by Roderic P. Quirk; Tae-Hee Cheong; Taejun Yoo


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
178 KB
Volume
203
Category
Article
ISSN
1022-1352

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Anionic synthesis of ฯ‰-dimethylamino-fun
โœ Quirk, Roderic P.; Han, Kwansoo; Lee, Youngjoon ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 310 KB

The functionalization reactions of polystyryllithium, polyisoprenyllithium and polybutadienyllithium in benzene with 3-dimethylaminopropyl chloride have been investigated in detail. The eรพ ects of addition mode (normal and inverse addition), added Lewis bases (THF and TMEDA), temperature and concent