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Synthesis of Functionalized Polymers by Means of Living Anionic Polymerization, 2. Synthesis of Well-Defined Chain-End and in-Chain Functionalized Polymers with 1,3-Butadienyl Groups

โœ Scribed by Naoki Haraguchi; Yoshihiko Sakaguchi; Kenji Sugiyama; Akira Hirao


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
153 KB
Volume
202
Category
Article
ISSN
1022-1352

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Synthesis of polymers containing conjuga
โœ Takahide Mizawa; Katsuhiko Takenaka; Tomoo Shiomi ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 154 KB ๐Ÿ‘ 2 views

In order to synthesize end-functionalized polymers with conjugated dienyl groups, living polymeric anions of polystyrene and polyisoprene were allowed to react with 5-bromo-1,3-pentadiene, 1, and 7-bromo-1,3-heptadiene, 2. The reaction of polystyryl anion and/or polyisoprenyl anion with 1 gave polym