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On the mechanism of the reaction K + Br2 → K+ + Br2− near the threshold

✍ Scribed by A.A. Zembekov

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
188 KB
Volume
11
Category
Article
ISSN
0009-2614

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✦ Synopsis

Analysis of the possible mechanisns of the reaction K + Bra -, K+ + Br; near the threshold is presented. It is assumed that the valence electron of an alkali atom is transferred to the halogen molecule at the intermolecular distance, depending upon the vertical electron @itity of the halogen molecule. Deactivation of the viiraf.ionaUy excited Bri ion occurs in the subsequent coUisir?n -with the K+ion and this protides the possiiility of the reaction under discussion.

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