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Observation of the reaction I*(2P12) + Br2 → IBr + Br*(2P12)

✍ Scribed by Paul L. Houston

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
484 KB
Volume
47
Category
Article
ISSN
0009-2614

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✦ Synopsis

The I*(* PI/z) + Brt 5z IBr + Br*(* Pr/z) reaction has been directly observed by monitoring both the decay of i* ftuorescence (1.3 p) and the appearance of Br* fluorescence (2.7 u) following laser photolysrs of i-CjF',I in flowing mLxtures with Brz and argon. The total rate for deactivation of I* by Brz, an upper limit on k*, is (1.95k 0.12) x IO6 S' to& , \here the uncertamty represents two standard deviations.

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