✦ LIBER ✦
Effect of spin—orbit excitation on chemical reactivity: Laser transient absorption spectroscopy of Br(2P12, 2P32 + IBr reactive dynamics
✍ Scribed by Harold K. Haugen; Eric Weitz; Stephen R. Leone
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 476 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
A laser pulse-and-probe technique
mcorporaling a tunable infrared color center laser is used ICI study the reactIons and quenching of Br(1P,,2. 2 P3,2 ) with 1%. A highly selestive spin-orb11 effecl on chemical reacG<lj is obsewed The ground-slaw reaction, BI-(~P,~)+IB~ + Br2+I, k = (46+0.6)~10-" cm' molecule-' s-' proceeds a~ a rate 2 40 limes faster than the raw of lolaI Br' quenching and reaction with IBr.