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Ion-pair (Br+ + Br−) formation from photodissociation of Br2 near the first ionisation limit

✍ Scribed by Andrew J. Yencha; Devinder K. Kela; Robert J. Donovan; Andrew Hopkirk; Agust Kvaran


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
465 KB
Volume
165
Category
Article
ISSN
0009-2614

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✦ Synopsis


Excitation functions for Br-and Br+ formation from jet-cooled Br,, in the region 120-I 14 nm (i.e. from threshold to above the ionisation limit of Br2). are reported. The mechanism for ion-pair formation is discussed in terms of homogeneous couphag between the 8pn Rydberg State and the D(O: ) ion-pair state, correlating with Br-( 'So) +Br' ( jP,).