๐”– Bobbio Scriptorium
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ON THE MECHANISM OF QUENCHING OF SINGLET OXYGEN BY AMINES-III. EVIDENCE FOR A CHARGE-TRANSFER-LIKE COMPLEX

โœ Scribed by ROBERT H. YOUNG; R. L. MARTIN; D. FERIOZI; D. BREWER; R. KAYSER


Book ID
114891855
Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
628 KB
Volume
17
Category
Article
ISSN
0031-8655

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Evidence for a charge-transfer mechanism
โœ Ned H. Martin; Charles W. Jefford ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented. Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a rate-determining charge-transfer complex.