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Evidence for a charge-transfer mechanism in the photo-oxygenation of an enamine

✍ Scribed by Ned H. Martin; Charles W. Jefford

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
238 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented. Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a rate-determining charge-transfer complex.

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