Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented. Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a rate-determining charge-transfer complex.
A charge transfer mechanism for the colour of rose quartz
✍ Scribed by Smith, G. ;Vance, E. R. ;Hasan, Z. ;Edgar, A. ;Runciman, W. A.
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 272 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0031-8965
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