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Oxygen quenching of charge-transfer excited states of ruthenium(II) complexes. Evidence for singlet oxygen production

✍ Scribed by Demas, J. N.; Diemente, D.; Harris, E. W.


Book ID
127092544
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
281 KB
Volume
95
Category
Article
ISSN
0002-7863

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The complex a-s-[(bpy)aRu(~-CHs)s14\* (bpy is 2 ,2'-bipyndine) has been prepared by methylation of (bpy)+Ru(~~~a]\*\*\_ Electrochemical studies show that introduction of the bound pyridinium group creates a chemically attached electron acce tor site (EXn = -0.76 V in 0.1 M [El@-C4H& ] PFs-acetonitnl