On the mechanism of electrochemical ion transfer reactions
β Scribed by O. Pecina; W. Schmickler; E. Spohr
- Publisher
- Elsevier
- Year
- 1995
- Tongue
- English
- Weight
- 525 KB
- Volume
- 394
- Category
- Article
- ISSN
- 1572-6657
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π SIMILAR VOLUMES
Electron and ion transfer reactions on metal electrodes are considered in an extended Anderson model, in which the interactions of the reactant with the metal and with the solvent depend on the separation from the interface. The model allows the construction of effective potential energy surfaces. E
The mechanism of the condensation reactions of CH 3 ions with CH4, NH 3 and H2S was studied. Apparently, neither a purely "direct" reaction nor complete equilibration of hydrogen atoms takes place. Evidence for intramolecular exchange of hydrogen atoms prior to H2 elimination was found.