On the mechanism of CO adsorption on a silica‐supported ruthenium catalyst
✍ Scribed by Margarita Kantcheva; Safak Sayan
- Book ID
- 110383775
- Publisher
- Springer US
- Year
- 1999
- Tongue
- English
- Weight
- 180 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1011-372X
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The 33C NhfR spectra of carbonaceous residue deposited on silica-supported rotheniurn catalysts during met&m&ion reveal the presence of at least three species. Based on chemical shifts, spin-spin relaxation times, and chemical treatment of the sampIes, these species are interpreted as carbides adsor
The effects of alloying Pd and Cu on the infrared spectra of adsorbed CO are firstly, enhancement of linearly adsorbed CO on Pd at the expense of bridged CO on Pd due to dilution of exposed ensembles of Pd by Cu. secondly. reduction in the extent of dipolar coupling between adjacent CO molecules aga