Preparation and use of a chiral amine ruthenium hydrogenation catalyst supported on mesoporous silica
✍ Scribed by Cuauhtemoc Pérez; Salud Pérez; Gustavo A Fuentes; Avelino Corma
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 118 KB
- Volume
- 197
- Category
- Article
- ISSN
- 1381-1169
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A parallel library of optically active bicyclic tertiary amines bearing N-chiral bridgehead nitrogen atoms was readily prepared by condensation of primary amines, cyclic amino acids and aldehydes. The enantiocontrolling ability of each of the library members was examined for the asymmetric alkylatio