An attempted inta-amolecular Stille coupling of a bis-stannyletheue proceeds not by ipsosubstitution (7-endo--cyclisation) but via a c/he substitution pathway (6-exo-cyclisation). Deuterium labelling studies and blank reactions are in consonance with a palladium ca\_rbene mechanism originally put fo
β¦ LIBER β¦
On the mechanism of cine substitution in the Stille reaction: New evidence for the intermediacy of Pd(0) carbenes
β Scribed by Vittorio Farina; M. Azad Hossain
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 191 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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