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Use of 19F CIDNP in reaction mechanism studies. Evidence for the intermediacy of benzyl anion in the reaction of benzyl halides with sodium naphthalene

✍ Scribed by J.W. Rakshys Jr.


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
221 KB
Volume
12
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


A possible overhauser mechanism for 19F
✍ F.J. Adrian πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 English βš– 325 KB

It is proposed that the high field IgF nuclear spin polarization observed in fhe producr of the reaction of tluorobenzyl halides with sodium naphthalene is not due to the usual radical pair mechanism, but rather to a build up of electron spin polarization in the intermediate benzyl radical combined