✦ LIBER ✦

A possible overhauser mechanism for 19F nuclear spin polarization in the reaction of fluorobenzyl halides with sodium naphthalene

✍ Scribed by F.J. Adrian

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 325 KB
Volume: 26
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)89067-6

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✦ Synopsis

It is proposed that the high field IgF nuclear spin polarization observed in fhe producr of the reaction of tluorobenzyl halides with sodium naphthalene is not due to the usual radical pair mechanism, but rather to a build up of electron spin polarization in the intermediate benzyl radical combined with electron-nuclear spin cross relaxation.