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On the limits of applicability of the classical trajectory equations in the two-state approximation

✍ Scribed by Anne M. Woolley; Svend Erik Nielsen


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
284 KB
Volume
21
Category
Article
ISSN
0009-2614

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✦ Synopsis


The intIoducticjn of an average trajectory is much more powerful than can be appreciated from the derivations of the classical equations. This is discussed and exemplified by systems for which the general conditions derived will not be necessary conditions of applicability.


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On the applicability of the classical tr
✍ Gert Due Billing πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 English βš– 343 KB

Ey using the classical trajectory equations and an average trajectory we have been able to predict the single quantum transitions for the one-dimensional atom-diatom collision problem to within lo-30%. The double quantum transiiions POZ ye correct to within at least a factor of two.